Asymmetric autocatalysis : the soai reaction /

Asymmetric Autocatalysis provides a comprehensive introduction to the topic of autocatalysis and an in-depth review of the current state of the research.

Bibliographische Detailangaben
Weitere Verfasser: Soai, Kenso (HerausgeberIn), Kawasaki, Tsuneomi (HerausgeberIn), Matsumoto, Arimasa (HerausgeberIn)
Format: Licensed eBooks
Sprache:Englisch
Veröffentlicht: London : Royal Society of Chemistry, [2023]
Schriftenreihe:RSC catalysis series ; no. 43.
Online-Zugang:https://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=3435646
Inhaltsangabe:
  • Intro
  • Title
  • Copyright
  • Contents
  • Chapter 1 Asymmetric Autocatalysis: The Soai Reaction, an Overview
  • 1.1 Introduction
  • 1.1.1 Characteristic Features of Life
  • 1.1.2 Origin of Homochirality and Amplification of Enantiomeric Excess
  • 1.2 Asymmetric Autocatalysis
  • 1.2.1 Principle of Asymmetric Autocatalysis
  • 1.2.2 Discovery of Asymmetric Autocatalysis of 5-Pyrimidyl, 3-Quinolyl, and 5-Carbamoyl-3-pyridyl Alkanols with Amplification of Enantiomeric Excess: The Soai Reaction
  • 1.2.3 Trajectory Leading to the Discovery of Asymmetric Autocatalysis
  • 1.2.4 The First Asymmetric Autocatalysis of 3-Pyridyl Alkanol
  • 1.2.5 Highly Enantioselective Asymmetric Autocatalysis
  • 1.2.6 Discovery of Asymmetric Autocatalysis with Amplification of Enantiomeric Excess. The Soai Reaction
  • 1.2.7 Investigation of the Mechanism of Asymmetric Autocatalysis
  • 1.3 Studies on the Origins of Homochirality by Using Asymmetric Autocatalysis
  • 1.3.1 Circularly Polarized Light
  • 1.3.2 Chiral Inorganic Crystals of Quartz, Cinnabar, Sodium Chlorate, Retgersite, and the Enantiotopic Face of Achiral Crystals of Gypsum
  • 1.3.3 Organic Crystals
  • 1.4 Absolute Asymmetric Synthesis
  • 1.4.1 Realization of Absolute Asymmetric Synthesis
  • 1.4.2 Absolute Asymmetric Synthesis under Solid-Vapor Conditions
  • 1.5 Chiral Hydrogen, Carbon, Oxygen, and Nitrogen Isotopomers Act as the Origin of Homochirality in Conjunction with Asymmetric Autocatalysis
  • 1.6 Various Chiral Materials Including Cryptochiral Compounds as Triggers for Asymmetric Autocatalysis
  • 1.7 Unusual Phenomena of the Reversal of the Sense of Enantioselectivities Detected by Asymmetric Autocatalysis
  • 1.8 Application of Asymmetric Autocatalysis for the Synthesis of Various Chiral Compounds
  • 1.9 Conclusions
  • Acknowledgements
  • References
  • Chapter 2 Asymmetric Autocatalysis Initiated by Enantioenriched Chiral Organic Compounds: The Link Between Circularly Polarized Light and Nearly Enantiopure Organic Compounds
  • 2.1 Introduction
  • 2.2 Asymmetric Autocatalysis Initiated by Various Chiral Compounds
  • 2.3 Chiral Discrimination of Cryptochiral Saturated Quaternary Hydrocarbons
  • 2.4 Correlation Between Circularly Polarized Light and Highly Enantioenriched Organic Compounds Mediated by Asymmetric Autocatalysis
  • 2.5 Conclusion
  • Acknowledgements
  • References
  • Chapter 3 Asymmetric Autocatalysis Triggered by the Chirality of Minerals, Organic Crystals, and Surfaces
  • 3.1 Crystal Chirality of Achiral Compounds
  • 3.2 Chirality of Minerals and Inorganic Crystals as a Trigger for Asymmetric Autocatalysis
  • 3.2.1 SiO2 Quartz
  • 3.2.2 Sodium Chlorate and Bromate
  • 3.2.3 Cinnabar HgS
  • 3.2.4 Retgersite
  • 3.3 Chirality of Organic Compounds

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